March 13, 2016

Wisconsin strontium levels among highest in U.S. drinking water supplies

Regulators are studying whether to set limits for strontium, which is suspected of having negative health effects, especially for babies and children

Vicky and Bud Harris of rural De Pere point out the filtration system they installed in their home that removes strontium and other contaminants from their drinking water. The U.S. Environmental Protection Agency is studying whether to begin regulating strontium, which is found in some of the highest concentrations in the nation in drinking water in eastern Wisconsin.

Kyle Bursaw/Press-Gazette Media

Vicky and Bud Harris of rural De Pere point out the filtration system they installed in their home that removes strontium and other contaminants from their drinking water. The U.S. Environmental Protection Agency is studying whether to begin regulating strontium, which is found in some of the highest concentrations in the nation in drinking water in eastern Wisconsin.

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For the past six years, Michael Schnur and his family have been drinking bottled water.

Already concerned that pollutants from the coal ash landfill near his home in Sheboygan County might be leaching into his private well, Schnur became even more fearful last year when he received a letter from the state Department of Health Services. It warned that elevated levels of a little-known, unregulated element — strontium — were found in his drinking water.

In follow-up email correspondence, the DHS said the landfill was not impacting Schnur’s water and that strontium occurs naturally in the groundwater. Schnur was advised to install a water softener, which works by replacing minerals like calcium, magnesium and strontium with sodium.

“I have a new baby (coming) in a couple months, which is why it’s really nerve-wracking,” Schnur said last spring. A healthy baby girl, Sophia, was born in August.

Schnur, who acknowledges he is no expert on water issues, remains on alert. His family continues to drink bottled water.

The federal Environmental Protection Agency has made a preliminary decision to begin regulating strontium.

However, in January, the agency delayed a final decision in order to collect additional information. The EPA wants to determine, among other things, whether treatment systems that remove strontium also would remove beneficial calcium, potentially making the effects of strontium on bones and teeth even worse.

EPA data from 2013 to 2015 suggest that some public water systems in eastern Wisconsin contain among the highest levels of strontium found anywhere in the country. Nationwide testing showed 73 of the 100 highest readings came from Wisconsin in communities including Waukesha, Brookfield, Germantown, Kaukauna, Wrightstown and Fond du Lac.

The EPA has set 4 milligrams of strontium per liter of water as the lifetime health advisory limit — in other words, the maximum level that anyone should routinely consume — and 25 mg/L as the short-term health advisory limit, meaning no one should consume that amount of strontium at any time.

Twenty-nine of the results found in the EPA testing in Wisconsin exceeded the EPA’s 25 mg/L short-term health advisory limit. The highest level found in that round of testing was 53 mg/L in Germantown in 2013.

Strontium-map

The level of strontium detected in Schnur’s well, 7.2 mg/L, is what DHS toxicologist Roy Irving described as “middle of the pack.”

University of Wisconsin-Green Bay geoscience professor John Luczaj said if the EPA confirms 4 mg/L as an enforceable maximum contaminant level, that would be a “big deal.” According to a study released in June by Luczaj and Kevin Masarik, a groundwater education specialist at the Center for Watershed Science and Education at UW-Stevens Point, strontium is present in the deep aquifer “throughout much of eastern Wisconsin.”

Hundreds of wells throughout the region are affected, including many municipal wells from the suburban Milwaukee metropolitan area north to Green Bay, they found. Particularly high levels were found in parts of Brown, Outagamie and Calumet counties, Luczaj and Masarik wrote.

Luczaj said that while water softeners and reverse osmosis systems can remove strontium, he does not believe that municipal water system customers can be forced to buy expensive treatment systems in order to safely drink their water.

Health effects unclear

As a currently unregulated contaminant, strontium is still a public health mystery. Limited studies suggest, however, that exposure to strontium at elevated levels could affect infants, children and young adults, as it mimics calcium and is absorbed by their developing bones.

Possible health effects from exposure to high levels of strontium range from “strontium rickets” — in which bones are shorter and more dense than normal — to other tooth and bone deformities, according to a Wisconsin DHS fact sheet.

Residents on private wells whose water is contaminated with strontium are for the most part on their own when it comes to securing safe drinking water. Some use bottled water; others have installed reverse osmosis or water softeners to remove strontium.

Dee J. Hall / Wisconsin Center for Investigative Journalism

Residents on private wells whose water is contaminated with strontium are for the most part on their own when it comes to securing safe drinking water. Some use bottled water; others have installed reverse osmosis or water softeners to remove strontium.

The EPA said certain populations are more sensitive to strontium’s harmful effects, including people with calcium deficiencies, kidney conditions and Paget’s disease.

Bud and Vicky Harris have taken precautions against contaminants in their well water in the home where they have lived for nearly 20 years in the town of Lawrence near De Pere. He is a retired UW-Green Bay professor of natural and applied sciences and she retired from her job as a water quality specialist based in Green Bay for UW-Madison’s Sea Grant Institute.

It is good they took action. A test in 2012 showed 28 mg/L of strontium in the water coming into their home — above the maximum short-term exposure limit recommended by the EPA. A 2013 test showed 22 mg/L, slightly below that limit.

Soon after moving into their home, the Harrises installed a water softener, iron removal system and reverse osmosis system because they were aware of local drinking water problems, especially arsenic. Vicky Harris said the couple has spent thousands of dollars on water treatment systems to remove contaminants.

“For us, it’s worthwhile. Water is health. Water is everything,” she said.

Vicky Harris wonders about the untreated water their son drank from a private well in Allouez near Green Bay before they moved to their current home when he was 8 years old. Their son has mottled enamel on his teeth, which she said could be related to the fluoride also present in the Green Bay area.

Strontium levels high

Some samples collected from public water systems in Washington and Waukesha counties turned up strontium concentrations as high as 53 and 37 mg/L, respectively, well above both the short- and long-term advisory levels set by the EPA.

Still, exactly what this means for people living in affected areas is not yet clear.

In calculating safe concentrations, the EPA considers body weight, drinking water intake and the level of exposure to a contaminant believed to be from drinking water, along with an estimate of the level of daily exposure from other sources. Irving explained that it is important to note that these factors differ among people, as does their nutritional status.

University of Wisconsin-Green Bay professor John Luczaj has documented several natural contaminants in Wisconsin’s groundwater, including strontium, which is found in high concentrations in parts of eastern Wisconsin.

UW-Green Bay

University of Wisconsin-Green Bay professor John Luczaj has documented several natural contaminants in Wisconsin’s groundwater, including strontium, which is found in high concentrations in parts of eastern Wisconsin.

“There are a lot of things that promote healthy bones, things like calcium, vitamin D,” Irving said. “Those all counter-balance risks from strontium.”

Said Luczaj: “Strontium is important, especially if you have young children. But if it’s just a little above the lifetime value, I wouldn’t worry about it. Unless the strontium is very high, I wouldn’t worry about it.”

When Schnur received notice of the elevated level of strontium in his well water, it reaffirmed his decision to keep using bottled water.

“I just don’t trust people when it comes to water. I really don’t,” Schnur said.

One of the reasons people may become alarmed when they find strontium in their water is the prominence of its radioactive relative, strontium-90, which is associated with above-ground nuclear testing. But it is naturally occurring strontium, which is not radioactive, that is found in Wisconsin.

Where high concentrations were found in places including Cedarburg, Germantown and Kiel, water utility managers there said more than 90 percent of homes already have water softeners. It is unclear, however, how many people are drinking the softened water, which some people avoid because it has added sodium. While drinking softened water is not considered harmful for most healthy adults, people on sodium-restricted diets are advised to consider other options.

Brookfield Water Utility Superintendent Mark Simon said most of his water customers already have water softeners. He said some people also have reverse osmosis systems, which force water through a semipermeable membrane to remove dissolved salts and contaminants.

Strontium problem centered on eastern Wisconsin

The samples from public water systems in Brookfield and others around the country were collected as part of the EPA’s Unregulated Contaminant Monitoring Rule program.

Under the Safe Drinking Water Act, the agency is required to decide whether to regulate at least five unregulated contaminants every five years. The act sets mandatory standards for public water systems.

Previous studies have estimated that strontium occurs at levels of concern in 7 percent of public water systems in the country. That information, coupled with the knowledge of its potential health effects, led the EPA to make a preliminary decision in 2014 to begin developing strontium regulation.

Before the EPA began collecting data in 2013, however, Luczaj, the UW-Green Bay professor, conducted a regional study of wells, focused on Brown and Outagamie counties, to map the distribution of strontium in the eastern part of the state and determine its source.

In his paper published in 2015, Luczaj found high levels of strontium in “an arc-shaped band through eastern Wisconsin from suburban Milwaukee up through Brown, Outagamie, Calumet, Door, Oconto and Marinette counties.”

overview map Final

Although Luczaj does not consider strontium to be among the most significant groundwater contaminants, he said it is something people should know about. He emphasized the state’s top water quality concerns are bacteria and nitrate, with up to half of the wells tested above health standards in some counties.

“Strontium’s probably more of a long-term issue, especially for children, but for adults it’s probably not as significant of a problem,” Luczaj said. “But we don’t know because there hasn’t been a lot of work on it.”

Geology affects strontium

Luczaj said strontium is present in such high levels in certain areas of Wisconsin because of the presence of a particular type of bedrock stretching from Illinois to Upper Michigan along the eastern part of the state.

Sometime between 200 million and 400 million years ago, water moved out of the deep sedimentary rock in Michigan into aquifers in Wisconsin.

Vicky and Bud Harris of rural De Pere remove pollutants from their drinking water using a reverse osmosis filtering system, a water softener and an iron removal system. The Harris’ private well water is tainted with strontium, which is a naturally occurring contaminant.

Kyle Bursaw / Press-Gazette Media

Vicky and Bud Harris of rural De Pere remove pollutants from their drinking water using a reverse osmosis filtering system, a water softener and an iron removal system. The Harris’ private well water is tainted with strontium, which is a naturally occurring contaminant.

That “precipitated a bunch of different minerals in different locations,” Luczaj said. “One of the minerals was strontium sulfate, called celestine, and that’s the mineral that is dissolving and causing the strontium problem.”

Other inorganic contaminants, such as arsenic and fluoride, are also related to the same water-rock interaction. Where they turn up depends on the chemistry in particular areas of the state. Luczaj said arsenic contamination in drinking water is further west, where oxidation is taking place, while strontium is farther east, where dissolution is happening.

Few concerns over strontium

Irving, the DHS toxicologist, shared Luczaj’s opinion that strontium “is not a concern for most people.”

“The groups of people that we might be a little more concerned about are life stages where kids’ … bones are developing,” Irving said. “And that’s just based off the animal studies that have shown that strontium maybe can affect bone development, but at a very high amount.”

Whatever the danger might be, aside from a select few residents, there does not seem to be much concern about strontium from members of the public.

Since Luczaj’s study was published and covered by local media, Brown County Public Health Sanitarian Marty Adams said he has only received a call or two.

Milwaukee posted this warning about high strontium levels in spring 2015 on the popular public well where residents fill up drinking water jugs in the city’s Bay View neighborhood. The U.S. Environmental Protection Agency is considering regulation of this naturally occurring metal, which is found in the highest concentrations nationwide in southeast Wisconsin. Consumption of strontium can lead to bone and tooth problems in children.

Katherine Keller / Bay View Compass

Milwaukee posted this warning about high strontium levels in spring 2015 on the popular public well where residents fill up drinking water jugs in the city’s Bay View neighborhood. The U.S. Environmental Protection Agency is considering regulation of this naturally occurring metal, which is found in the highest concentrations nationwide in southeast Wisconsin. Consumption of strontium can lead to bone and tooth problems in children.

“I think a lot of people just don’t understand what it is and therefore not a lot of questions have developed about it,” Adams said.

Tests of Adams’ own well water have uncovered levels of strontium between 16 and 17 mg/L, far above the EPA’s long-term health advisory level of 4 mg/L. Due to the high levels of fluoride present when Adams’ well was drilled 20 years ago, he already had a reverse osmosis system and water softener installed.

The concern is for “those that are not using softeners or reverse osmosis or distilled water or some other type of treatment that would take it out,” Adams said.

Adams emphasized that for private wells, it is up to individual homeowners to have their water tested. One resource is the State Laboratory of Hygiene. A test for heavy metals, including strontium, lead, arsenic, manganese and other elements, costs $60.

People drinking municipal water may also want to do testing, as the EPA is not likely to begin regulating strontium anytime soon.

While Schnur has tried to get his neighbors to test their water, he said the interest just has not been there.

“I just wanted people to be notified of it — that there were high levels of strontium — and it doesn’t seem like anyone really cares,” Schnur said. “Each to their own. I’m just going to make sure my family’s safe.”

  • ZeeXenon

    So what! We’ve lived with radium-laced water for 45 years, and a warning
    on the back of each and every water bill. Thanks for nothing, dearest
    government. The warning says something like, “…no need for immediate
    concern….” Well, isn’t that just wonderful you weasels.

  • disqus_s18WFM2FBN

    It is important to think of the developing fetus, infant and child in a different way. Infants will likely absorb more as the infant gut is more permeable than that of an adult…They will also take in a larger amount of water when viewed as mg/kg basis…From 0-6 months, breastmilk or formula is their entire diet..another factor that makes the exposure greater in infants. Infants and children also put everything in their mouth, including dirt…which can increase exposure. Because children are actively laying down new bone, Sr acts like Ca and is incorporated into bone. On so many levels, this is very concerning.

    2 questions that I have are:
    1) Is coal ash (Sr is found in this waste product) being spread in any of these areas that could increase the concentration of Sr?
    2) Do any of the Britta or Pur systems remove Sr?

    One more point…officials mentioned that softening water removes it…but often the cold drinking water is not softened.

    Thanks for keeping us informed on environmental issues in WI.